Here’s another great pair of complements: pyrol ruby and viridian. Both of these are from Robert Doak. Pyrol ruby is a fairly transparent modern organic lake pigment with a color similar to alizarin crimson. It is quite permanent. Viridian is semi-transparent and slightly on the bluer side of green.
The ruby is a much stronger tinter than viridian. They mix to a very dark neutral that can substitute for black.

I strongly encourage any painter to do these kinds of experiments with all combinations of the paints they typically keep on their palette.
Tags: color, complementary colors, mixing pairs, paint mixing, paint swatches

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